Atomistry » Platinum » Chemical Properties » Calcium Platinocyanide
Atomistry »
  Platinum »
    Chemical Properties »
      Calcium Platinocyanide »

Calcium Platinocyanide, CaPt(CN)4

Calcium Platinocyanide, CaPt(CN)4.5H2O, may be prepared in a similar manner to the barium salt. It crystallises in rhombic prisms, having the following crystallographic elements:

a:b: с = 0.89956: 1: 0.34943

Levy has shown that two isomeric varieties of the pentahydrate exist, analogous to the two isomerides of the tetrahydrate of barium platinocyanide. The a-salt may be described as golden yellow with green fluorescence on the pyramid faces, whilst the β-salt shows a green fluorescence on all faces, which is particularly intense on the tops of the crystals. The crystalline characters of the two isomerides are identical.

The α-salt is obtained by crystallisation from a solution containing a small quantity of acid, and the β-salt from one containing some hydroxyl or cyanide ions, precisely as in the case of the α and β barium platinocyanides.

Anhydrous calcium platinocyanide, CaPt(CN)4, is white, and exhibits only a feeble fluorescence.

Last articles

Zn in 7NN0
Zn in 7NIO
Zn in 7LUP
Zn in 7M1Y
Zn in 7LO4
Zn in 7KWO
Zn in 7KJY
Zn in 7KCQ
Zn in 7KC2
Zn in 7KCB
© Copyright 2008-2020 by atomistry.com
Home   |    Site Map   |    Copyright   |    Contact us   |    Privacy