|
Atomistry » Platinum » Chemical Properties » Monocarbonyl Platinum Di-iodide | ||
Atomistry » Platinum » Chemical Properties » Monocarbonyl Platinum Di-iodide » |
Monocarbonyl Platinum Di-iodide, PtI2.CO
Monocarbonyl Platinum Di-iodide, PtI2.CO, is obtained by adding dilute hydriodic acid to a solution of the carbonyl platinum dichloride in hydrochloric acid:
PtCl2CO + 2HI = PtI2.CO + 2HCl. A brick-red, amorphous precipitate is obtained. This is purified by solution in and recovery from hydriodic acid and subsequent recrystallisation from benzene. It may also be obtained by evaporating the mixed carbonyl derivatives, obtained by Schutzenberger's method, with concentrated hydriodic acid, and recrystallising from benzene. It yields red crystals, exhibiting a violet shimmer. They melt at 140° to 150° C., and decompose as the temperature is still further raised. They are decomposed by water rather slowly, whilst alkalies liberate metallic platinum. With potassium iodide a double salt, PtI2.CO.KI, is obtained as yellowish brown scales, which melt at 150° to 180° C. with decomposition. Other salts have been prepared, both with inorganic and with organic iodides. |
Last articlesZn in 8WB0Zn in 8WAX Zn in 8WAU Zn in 8WAZ Zn in 8WAY Zn in 8WAV Zn in 8WAW Zn in 8WAT Zn in 8W7M Zn in 8WD3 |
© Copyright 2008-2020 by atomistry.com | ||
Home | Site Map | Copyright | Contact us | Privacy |