Atomistry » Platinum » Chemical Properties » Tetrachlor-dihydroxy-platinic Acid
Atomistry »
  Platinum »
    Chemical Properties »
      Tetrachlor-dihydroxy-platinic Acid »

Tetrachlor-dihydroxy-platinic Acid, H2PtCl4(OH)2

Tetrachlor-dihydroxy-platinic Acid, H2PtCl4(OH)2 or PtCl4.2H2O, is obtained in solution by hydrolysing silver hexaehlor-platinate with boiling water:

Ag2PtCl6 + 2H2O = 2AgCl + H2PtCl4(OH)2,

and exists in solution when platinum tetrachloride is dissolved in water.

Upon concentrating the solution and heating the residue to 100° C. the monohydrate of platinic chloride, PtCl4.H2O, is obtained. Further dehydration cannot be effected in this manner without decomposition of the salt.

The solution has an acid reaction, decomposing carbonates. Titration with alkali, using phenolphthalein as indicator, shows that the acid is dibasic.

Several salts of this acid have been prepared. The silver salt, Ag2PtCl4(OH)2, has long been known. Other salts are those of zinc, ZnPtCl4(OH)2.3H2O; cadmium, CdPtCl4(OH)2; lead, PbPtCl4(OH)2, and a basic lead salt, PbPtCl4(OH)2.Pb(OH)2.

Last articles

Zn in 9MJ5
Zn in 9HNW
Zn in 9G0L
Zn in 9FNE
Zn in 9DZN
Zn in 9E0I
Zn in 9D32
Zn in 9DAK
Zn in 8ZXC
Zn in 8ZUF
© Copyright 2008-2020 by atomistry.com
Home   |    Site Map   |    Copyright   |    Contact us   |    Privacy