Atomistry » Platinum » Chemical Properties » Tetrachlor-dihydroxy-platinic Acid
Atomistry »
  Platinum »
    Chemical Properties »
      Tetrachlor-dihydroxy-platinic Acid »

Tetrachlor-dihydroxy-platinic Acid, H2PtCl4(OH)2

Tetrachlor-dihydroxy-platinic Acid, H2PtCl4(OH)2 or PtCl4.2H2O, is obtained in solution by hydrolysing silver hexaehlor-platinate with boiling water:

Ag2PtCl6 + 2H2O = 2AgCl + H2PtCl4(OH)2,

and exists in solution when platinum tetrachloride is dissolved in water.

Upon concentrating the solution and heating the residue to 100° C. the monohydrate of platinic chloride, PtCl4.H2O, is obtained. Further dehydration cannot be effected in this manner without decomposition of the salt.

The solution has an acid reaction, decomposing carbonates. Titration with alkali, using phenolphthalein as indicator, shows that the acid is dibasic.

Several salts of this acid have been prepared. The silver salt, Ag2PtCl4(OH)2, has long been known. Other salts are those of zinc, ZnPtCl4(OH)2.3H2O; cadmium, CdPtCl4(OH)2; lead, PbPtCl4(OH)2, and a basic lead salt, PbPtCl4(OH)2.Pb(OH)2.

Last articles

Cl in 5YFT
Cl in 5YFY
Cl in 5YFS
Cl in 5YFC
Cl in 5YFJ
Cl in 5YEA
Cl in 5YB0
Cl in 5Y9N
Cl in 5YDV
Cl in 5YD2
© Copyright 2008-2020 by atomistry.com
Home   |    Site Map   |    Copyright   |    Contact us   |    Privacy